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Coming from a long line of theory crafting in WoW and a long time diablo 2 player, my rule of thumb on this is anything that can get you a higher max damage is gong to net you higher dps as a result in the end; Regardless of proc chance and what not. I will be switching to devouring as I use Puncturing atm for the 50% pierce. I'd rather have a 35% chance and double my damage a few times, ESPECIALLY, if you have increased crit damage.
I wish I could number crunch this but this is hardly the place nor time :P
Good luck, just experiment.
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