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You have to play Maw of the Void to get to Char. You have to play Supernova to get to Maw of the Void. Supernova requires fourteen total missions to unlock.
Supernova is fifteen, MotV is sixteen and three more on Char makes nineteen.
The list Azire provided looks like the quickest route.
It's worth noting that it's not much of an challenge to accomplish those nineteen missions in eight hours; a bit of a yawner in fact.
Try to get this achievement playing through all 29 missions and acquiring all research points
That's what I'm doing now
02"07 Liberation Day
02"37 The Outlaws
20"05 Zero Hour
23"30 The Evacuation
03"39 The Devil's Playground
11"31 Outbreak (did 11"28 in another run before, quitted trying to improve it this time)
03"40 Smash and Grab
06"52 Welcome to the Jungle
27"42 The Dig
09"27 Whispers of Doom
05"00 A Sinister Turn
01"54 Echoes of the Future
34"42 In Utter Darkness
23"41 The Great Train Robbery
08"43 The Moebius Factor
Have fun squeezing on the times
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