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I think that depends on how much of a stockpile you have when cata starts.
I know I have enough cooking mats to make a few dozen fish feasts, so that's how I'll start off cooking (fish feast is orange at 450). Similarly, I have a decent stockpile of enchanting mats I intend to use for the early levels.
I have yet to look into tailoring, though, but cloth tends to fall from trees anymore.
Yes, most of the professions you can level to 465 with wrath mats. I did test out enchanting in the beta, I followed a guide I found at DPI Gaming http://www.dpigaming.com/index/2010/11/16/enchanting-guide-for-cataclysm-450-to-525.html
I was able to reach 475 with wrath mats using the bracers - major stamina. But I don't know if they're going to change that recipe after the beta.
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