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I can't confirm this works or not, but from my experience I'm leaning towards he didn't miss out on much.
I did the last 6 bosses on LFR this week to finish my secrets of the empire, then in normal raids we just finished the last 3 normals today (Iron Qon, Twins, and Lei Shen) and received 0/3. With how legendary quest drop rates are, not to say that's any real evidence, but I wouldn't fret too much about trying to get them in the same week you finish secrets.
It's safe to assume that Titan Runestones work the same as Secrets of the Empire, where you only get one shot per boss per week regardless of which difficulty it's killed on. So, there's no reason to run any of the bosses on LFR unless you sat for one of those bosses in your regular raid at some point. The only difference is that there's half the bosses eligible to begin with (the back six).
Edited by Thecheat on 5/4/2013 1:55 AM PDT
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